16. Solving a chemistry problem
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5. A weighing of the adjusting substance of sodium carbonate weighing 0.2500 g was dissolved in a volumetric flask with a capacity of 50 ml and the solution was brought to the mark with glacial acetic acid. Potentiometric titration of 5 ml of the resulting solution with perchloric acid in anhydrous acetic acid gave the following results:
V(HClO4), ml 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20
E, mV 431 439 450 465 486 523 550 566 575
Construct a titration curve in the coordinates ΔE / ΔV - V and calculate the molar concentration of the sodium carbonate equivalent of the perchloric acid solution.
V(HClO4), ml 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20
E, mV 431 439 450 465 486 523 550 566 575
Construct a titration curve in the coordinates ΔE / ΔV - V and calculate the molar concentration of the sodium carbonate equivalent of the perchloric acid solution.
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