46. Solving a chemistry problem
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13. Calculate the heat of micellization, as well as the standard Gibbs energy and entropy of the process at 293 K, using the following CMC values for sodium dodecyl sulfate in NaCl solutions:
T,K 293 311 333
CMC, mmol/l
in 0.01 M NaCl solution 5.13 5.37 6.17
in 0.2 M NaCl solution 0.76 0.87 1.45
Analyze the change in the thermodynamic functions of micelle formation and the effect of the electrolyte.
T,K 293 311 333
CMC, mmol/l
in 0.01 M NaCl solution 5.13 5.37 6.17
in 0.2 M NaCl solution 0.76 0.87 1.45
Analyze the change in the thermodynamic functions of micelle formation and the effect of the electrolyte.
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